Professor Patricia J. Kooyman
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Professor
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Overview/ Research interests
Synthesis and characterisation of nanoparticles and their application in catalysis.
Supported and unsupported metallic, oxidic and sulphidic catalysts. Zeolites and porous materials.
Fischer-Tropsch catalysis, reduction-oxidation catalysis, hydrocarbon processing, wax upgrading, hydrodesulphurisation, photocatalysis, electrocatalysis.
High resolution transmission electron microscopy and in situ transmission electron microscopy.
Education
MSc: Leiden University, The Netherlands
PhD: Delft University of Technology, The Netherlands
Experience
Post-Doc:
Shell Research, Amsterdam, The Netherlands
National Centre for HREM, Delft, The Netherlands
Faculty:
Department of Chemical Engineering, Faculty of Applied Sciences, Delft University of Technology, The Netherlands
Major grants and Awards
Part of NIMIC consortium for the development of in situ TEM and SPM equipment
Publications
1988
1 T.L.F. Favre, P.J. Seijsener, P.J. Kooyman, A. Maltha, A.P. Zuur and V. Ponec,
Catal. Lett. 1 (1988) 457. Selective reduction of nitrobenzene to
nitrosobenzene on oxidic catalysts.
2 T.L.F. Favre, A. Maltha, P.J. Kooyman, A.P. Zuur and V. Ponec, Proceedings of
the XI Iberoamerican Catalysis Symposium, Guanajuato 1988, Vol II, p.
807. Selective reduction of nitrobenzene to nitrosobenzene catalysed by
manganese oxides.
1990
3 P.J. Kooyman, Appl. Catal. 66 (1990) N26. Meeting report: 13th annual
meeting of the British zeolite association.
1992
4 P.J. Kooyman, P. Van der Waal, P.A.J. Verdaasdonk, J.C. Jansen and H. Van
Bekkum, Catal. Lett. 13 (1992) 229. Titanium deposited from TiCl4 on
amorphous silica and silicalite-1 as catalyst in aromatic hydroxylation
reactions.
1993
5 J.A. Martens, Ph. Buskens, P.A. Jacobs, A. van der Pol, J.H.C. van Hooff, C.
Ferrini, H.W. Kouwenhoven, P.J. Kooyman and H. van Bekkum, Appl. Catal.
A: General 99 (1993) 71. Hydroxylation of phenol with hydrogen peroxide on
Euro-TS-1 catalyst.
6 P.J. Kooyman, J.C. Jansen and H. van Bekkum, Proceedings of the 9th
International Zeolite Conference, Montreal 1992, eds. R. von Ballmoos et
al., Butterworth-Heinemann, USA, 1993, p.505. Characterisation and
catalytic properties of titanium incorporated into zeolites and silicas from
titanium trifluoride.
1996
7 P.J. Kooyman, H.W. Zandbergen, K.R. Kloetstra and H. van Bekkum,
Proceedings of the 11th European Congress on Electron Microscopy
EUREM '96, Dublin, 1996, CD-rom. MCM-41: A transmission electron
microscopy study. Also in print: Volume 2, pp II-38 through II-39. Brussels
1998.
8 P.J. Kooyman, G.C.A. Luijkx, A. Arafat and H. van Bekkum, J. Molec. Catal.
111 (1996) 167. Microwave heating in the TS-1 catalysed oxyfunctionalisation
of n-hexane.
9 E.J. Creyghton, A.C.T. van Duin, J.C. Jansen, P.J. Kooyman, H.W. Zandbergen
and H. van Bekkum, J. Chem. Soc., Faraday Trans., 92 (1996) 4637.
Synthesis of Pt clusters in zeolite BEA: effect of reduction rate on cluster size
and location.
1997
10 P.J. Kooyman, P. van der Waal and H. van Bekkum, Zeolites 18 (1997) 50. Acid
dealumination of ZSM-5.
11 A. Lagerwaard, K.J. Volkers, D. Camelot, P.J. Kooyman and J. van Geel,
Proceedings of Workshop on the status of measurement techniques for
the identification of nuclear signatures, Geel (B) 1997, EUR 17312 EN p.
115. Preparation and characterization of micrometre size nuclear material
particles for analytical studies: a need for definition.
53 D. Camelot, K-L Chou, P.J. Kooyman, J.C.M. Marijnissen, B. Scarlett and J.P.
Borra, J. Aerosol Sci. 28 (1997) S529-S530. Production of various ceramic
powders using bipolar mixing.
1998
12 I. Peeters, A.W. Dernier van der Gon, M. Reijme, P.J. Kooyman, A.M. de Jong,
J. van Grondelle, H.H. Brongersma and R.A. van Santen, J. Catal. 173 (1998)
28. Structure-activity relationships in the oxidative ammonolysis of ethylene
over γ-Al2O3 supported molybdenum oxide catalysts.
13 F. Cot, P.J. Kooyman, A. Larbot and E. Prouzet, SSSC 117 (1998) 231.
(Mesoporous Molecular Sieves 1998, eds L. Bonneviot, F. Beland, C.
Danumah, S. Giasson and S. Kaliaguine) Improved synthesis of MSU-X silica
prepared by polyethylene oxide surfactants.
14 H.W. Zandbergen, P.J. Kooyman and A.D. van Langeveld, Electron
Microscopy 1998, proceedings ICEM 14, Cancun, Mexico, 31 August to 4
September 1998, Symposium W, Volume II, pp 491-492. Transfer systems
for insertion of specimens into electron microscopes under controlled
atmospheres.
15 H.R. Reinhoudt, A.D. van Langeveld, P.J. Kooyman, R.M. Stockmann, R. Prins,
H.W. Zandbergen and J.A. Moulijn, J. Catal. 179 (1998) 443-450. The
evolution of the surface species in NiW/Al2O3 catalysts in various stages of
sulfidation: A quasi in-situ high resolution electron microscopy investigation.
16 J.C. van der Waal, P.J. Kooyman, J.C. Jansen and H. van Bekkum,
Microporous and Mesoporous Materials 25 (1998) 43-57. Synthesis and
characterisation of aluminium-free zeolite titanium beta using
di(cyclohexylmethyl)dimethylammonium as a new and selective template.
1999
17 M.J. Verhoef, P.J. Kooyman, J.A. Peters and H. van Bekkum, Microporous and
Mesoporous Materials 27 (1999) 365-371. A study on the stability of
MCM-41 supported heteropoly acids under liquid- and gas-phase
esterification conditions.
18 E. Prouzet, F. Cot, G. Nabias, A. Larbot, P.J. Kooyman and T.J. Pinnavaia,
Chem. Mater. 11 (1999) 1498-1503. Assembly of Mesoporous Silica
Molecular Sieves Based on Nonionic Ethoxylated Sorbitan Esters as Structure
Directors.
19 J.P. Borra, D. Camelot, K-L Chou, P.J. Kooyman, J.C.M. Marijnissen and B.
Scarlett, J. Aerosol Sci. 30 (1999) 945-958. Bipolar Coagulation for powder
production: Micro-mixing inside droplets.
20 P.J. Kooyman, J.G. Buglass, H.R. Reinhoudt, A.D. van Langeveld, H.W.
Zandbergen and J.A.R. van Veen, Europacat IV book of abstracts (1999)
466. Quasi in situ sequential sulphidation of CoMo/Al2O3 studied using High
Resolution Electron Microscopy.
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21 J.C. Jansen, Z. Shan, L. Marchese, P.J. Kooyman and Th. Maschmeyer,
Europacat IV book of abstracts (1999) 127. TUD-1, a new generation of
ultrastable silicas with three-dimensionally connected meso- and micropore
networks.
22 L. Simon, J.G. van Ommen, P.J. Kooyman, A. Jentys and J.A. Lercher, DMKG
Tagungsbericht 9903, conference "The future role of aromatics in refining
and petrochemistry', Erlangen, Germany, October 13-15, 1999, pp
177-184. Sulphur tolerance of alkali exchanged zeolites for benzene
hydrogenation.
23 T. Mallat, S. Frauchiger, P.J. Kooyman, M. Schürch and A. Baiker. Catal. Lett.
63 (1999) 121-126. Restructuring during pretreatment of platinum/alumina
for enantioselective hydrogenation.
2000
24 R.J.H. Grisel, P.J. Kooyman and B.E. Nieuwenhuys. J. Catal. 191 (2000)
430-437. Influence of the preparation of Au/Al2O3 on the CH4 oxidation
activity.
25 P.J. Kooyman, M.J. Verhoef and E. Prouzet, Proceedings Nanoporous
Materials II, SSSC 129 (2000) 535-542. Banff, Alberta, Canada, May 25-30,
2000. Eds. A. Sayari, M. Jaroniec, T. Pinnavaia. Transmission Electron
Microscopy – an indispensable tool for the characterisation of M41S-type
materials.
26 C. Boissière, A. Larbot, A. van der Lee, P.J. Kooyman and E. Prouzet, Chem.
Mater. 12 (2000) 2902-2913. A new synthesis of mesoporous MSU-X silica
controlled by a two-step pathway.
27 E. Toukoniitty, P. Mäki-Arvela, A.N. Villela, A. Kalantar-Neyestanaki, T. Salmi,
R. Leino, R. Sjöholm, E. Laine, J. Väyrynen, T. Ollonqvist, and P.J.
Kooyman, Catal. Today 60 (2000) 175-184. The effect of oxygen and the
reduction temperature of the Pt/Al2O3 catalyst in enantioselective
hydrogenation of 1-phenyl-1,2-propanedione
28 H.R. Reinhoudt, E. Crezee, A.D. van Langeveld, P.J. Kooyman, J.A.R. van
Veen and J.A. Moulijn, J. Catal. 196 (2000) 315-329. Characterization of the
active phase in NiW/γ-Al2O3 catalysts in various stages of sulfidation with
FTIR(NO) and XPS.
29 F. Devred, P.J. Kooyman and H.W. Zandbergen, Jaarboek 2000 Nederlandse
Vereniging voor Microscopie, (2000) p. 52-53. A TEM/HREM study of
Raney-type catalysts.
91 R.D. Vis, A. Mwowiec, P.J. Kooyman and D. Heymann, Meteoritics and
planetary science 35 (2000) A165. Carbon nanobottle carriers of planetary
noble gases in Meteorites.
2001
30 F. Devred, P.J. Kooyman and H.W. Zandbergen, Proceedings NCCC II,
Noordwijkerhout, The Netherlands, March 5-7, 2001 p. 234. A TEM/
HREM study of Raney-type catalysts.
31 E.J.M. Hensen, P.J. Kooyman, Y. van der Meer, A.M. van der Kraan, V.H.J. de
Beer, J.A.R. van Veen, R.A. van Santen, J. Catal. 199 (2001) 224-235. The
relation between morphology and hydrotreating activity for supported MoS2
particles.
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32 P.J. Kooyman, M. Slabova, V. Bosacek, J. Cejka, J. Rathousky, and A. Zukal,
Coll. Czech. Chem. Commun. 66 (2001) 555-566. The influence of pH on
the structure of templated mesoporous silicas prepared from sodium
metasilicate.
33 M.J. Verhoef, P.J. Kooyman, J.C. van der Waal, M.S. Rigutto, J.A. Peters, H.
van Bekkum, Chem. Mater. 13 (2001) 683-687. Partial transformation of
MCM-41 material into zeolites: formation of nanosized MFI type crystallites.
34 P.J. Kooyman, E.J.M. Hensen, A.M. de Jong, J.W. Niemantsverdriet, J.A.R. van
Veen, Catal. Lett. 74 (2001) 49-53. The observation of nanometer-sized
entities in sulphided Mo-based catalysts on various supports.
35 J. Rathousky, J. Cejka, P.J. Kooyman, M. Slabova and A. Zukal, SSSC 135,
Proc. 13th IZC, Montpellier, France, July 8-13, 2001. A06P20. Controlling
the assembly of silica mesoporous materials by varying the decrease in pH.
36 E. Toukoniitty, B. Secikova, N. Kumar, P. Mäki-Arvela, T. Salmi, J. Väyrynen,
T. Ollonqvist, E. Laine, P.J. Kooyman, and D.Y. Murzin, SSSC 135, Proc.
13th IZC, Montpellier, France, July 8-13, 2001. A23P25. Synthesis and
characterisation of mesoporous Pt-MCM-41and its application in
enantioselective hydrogenation of 1-phenyl-1,2-propanedione.
37 P.J. Kooyman, P. Waller, A.D. van Langeveld, C. Song, K. M. Reddy and J.A.R.
van Veen, Recent Research Reports, 13th IZC, Montpellier, France, July
8-13, 2001. 26-R-02. MCM-41 as a support for CoMoS hydrotreating
catalysts.
38 B. Lindlar, A. Kogelbauer, P.J. Kooyman, and R. Prins, Microporous and
Mesoporous Materials 44-45 (2001) 89-94. Synthesis of Large Pore Silica
and Silica-alumina with a Narrow Pore Size Distribution.
39 E. Toukoniitty, P. Mäki-Arvela, A. Kalantar-Neyestanaki, T. Salmi, R. Sjöholm,
R. Leino, E. Laine, P.J. Kooyman, T. Ollonqvist and J. Väyrynen, Appl.
Catal. A: General 216 (2001) 73-83. Batchwise and continuous
enantioselective hydrogenation of 1-phenyl-1,2-propanedione catalysed by
new Pt/SiO2 fibers.
40 P.J. Kooyman, E.J.M. Hensen, A.M. de Jong, J.W. Niemantsverdriet and J.A.R.
van Veen, Proc. Europacat V, Limerick, Ireland, September 2-7, 2001. 20-
P-17. The observation of nanometer-sized entities in sulphided Mo-based
catalysts on various supports.
41 F. Devred, B. Hoffer, P.J. Kooyman and H.W. Zandbergen, Proc. Europacat V,
Limerick, Ireland, September 2-7, 2001. 6-P-14. Raney-type nickel
catalysts: a HREM study.
42 B. Hoffer, F. Devred, A.D. van Langeveld, P.J. Kooyman, R.L.C Bonné, C.M.
Lok and J.A. Moulijn, Proc. Europacat V, Limerick, Ireland, September
2-7, 2001. 13-P-02. Activation behaviour of ex-situ presulfided Ni/Al2O3
catalysts for pyrolysis gasoline hydrogenation: temperature programmed
studies.
43 J. Hajek, E. Toukoniitty, P. Kacer, P. Mäki-Arvela, L. Cerveny, N. Kumar, D.
Yu. Murzin, T. Salmi, E. Laine, P.J. Kooyman, T. Ollonqvist and J. Väyrynen,
Proc. Europacat V, Limerick, Ireland, September 2-7, 2001. 16-P-12.
Preparation and properties of Ru-Sn sol-gel catalysts.
44 E. Toukoniitty, P. Mäki-Arvela, A. Kalantar-Neyestanaki, T. Salmi, D. Yu.
Murzin, E. Laine, P.J. Kooyman, T. Ollonqvist and J. Väyrynen, Proc.
Europacat V, Limerick, Ireland, September 2-7, 2001. 16-P-13. Transient
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studies in complex enantioselective hydrogenation - kinetics, regio- and
enantioselectivity.
45 N. Maxim, P.C.M.M. Magusin, P.J. Kooyman, J.H.M.C. van de Wolput, R.A.
van Santen and H.C.L. Abbenhuis, Chem. Mater. 13 (2001) 2958-2964.
Microporous Mg-Si-O and Al-Si-O materials derived from metal
silsesquioxanes.
46 R. Huq, L. Mercier and P.J. Kooyman, Chem. Mater. 13 (2001) 4512-4519.
Incorporation of cyclodextrin into mesostructured silica.
74 M. McInall, J. Scott, L. Mercier and P.J. Kooyman, Chem. Commun. (2001)
2282-2283. Super-microporous organic-integrated silica prepared by nonelectrostatic
surfactant.
2002
47 M.K. Oudenhuijzen, P.J. Kooyman, B. Tappel, J.A. van Bokhoven and D.C.
Koningsberger, J. Catal. 205 (2002) 135-146. Understanding the Influence of
the Pretreatment Procedure on Platinum Particle Size and Particle-Size
Distribution for SiO2 impregnated with [Pt2+(NH3)4](NO3-)2: a combination of
HRTEM, mass spectrometry and quick EXAFS.
48 Lu Gang, B.G. Anderson, J. van Grondelle, R.A. van Santen, W.J.H. van
Gennip, J.W. Niemansverdriet, P.J. Kooyman, A. Knoester and H.H.
Brongersma, J. Catal. 206 (2002) 60-70. Alumina-supported Cu-Ag catalysts
for ammonia oxidation at low temperature.
49 M. Sun, P.J. Kooyman, and R. Prins, J. Catal. 206 (2002) 368-375. A High-
Resolution Transmission Electron Microscopy Study of the Influence of
Fluorine on the Morphology of WS2 in Sulfided W/Al2O3 and NiW/Al2O3
catalysts.
50 B. W. Hoffer, F. Devred, P.J. Kooyman, A.D. van Langeveld, R.L.C. Bonné, C.
Griffiths, C.M. Lok and J.A. Moulijn, J. Catal. 209 (2002) 245-255.
Characterisation of ex-situ presulphided Ni/Al2O3 catalysts for pyrolysis
gasoline hydrogenation.
51 E. Prouzet, F. Cot, C. Boissière, P.J. Kooyman, and A. Larbot, J. Material.
Chem. 12 (2002) 1553-1556. Nanometric hollow spheres made of MSU-Xtype
mesoporous silica.
52 P.J. Kooyman, Second FEZA Conference, Book of Abstracts and Recent
Research Reports, Impact of zeolites and other porous materials on the
new technologies at the beginning of the new century. RRR 028. TEM/
HREM characterisation of Fe/ZSM-5.
54 F.R. van den Berg, M.W.J. Crajé, P.J. Kooyman, A.M. van der Kraan and J.W.
Geus, Appl. Catal. A: General 235 (2002) 217-224. Synthesis of Highly
Dispersed Zirconia-Supported Iron-Based Catalysts for Fischer-Tropsch
Synthesis.
55 J. Cejka, P.J. Kooyman, L. Vesela, J. Rathousky and A. Zukal, PCCP 4 (2002)
4823-4829. Post-synthesis thermal restructuring of organised mesoporous
alumina.
56 N. Maxim, A. Overweg, P.J. Kooyman, J.H.M.C. van Wolput, R.W.J.M.
Hanssen, R.A. van Santen and H.C.L. Abbenhuis, J. Phys. Chem. B 106
(2002) 2203-2209. Synthesis and characterisation of microporous Fe-Cr-Si-O
materials with tailored iron content from silsesquioxane precursors.
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57 P.J. Kooyman, J.G. Buglass, H.R. Reinhoudt, E.J.M. Hensen, A.D. van
Langeveld, H.W. Zandbergen and J.A.R. van Veen J. Phys. Chem. B 106
(2002) 11795-11799. Quasi in situ sequential sulphidation of CoMo/Al2O3
studied using High Resolution Electron Microscopy.
75 R.D. Vis, A. Mwowiec, P.J. Kooyman, K. Matsubara and D. Heymann,
Meteoritics and planetary science 37 (2002) 1391-1399. Microscopic search
for the carrier phase Q of the trapped planetary noble gases in Allende,
Leoville and Vigarano.
76 N. Maxim, A. Overweg, P.J. Kooyman, A. Nagy, R.A. van Santen and H.C.L.
Abbenhuis, J. Mater. Sci. 12 (2002) 3792-3798. Synthesis and
characterisation of microporous bimetallic Fe-Cr-Si-O materials derived from
silsesquioxane precursors.
2003
58 A.A. Battiston, J.H. Bitter, F.M.F. de Groot, A.R. Overweg, O. Stephan, J.A.
van Bokhoven, P.J. Kooyman, C. van der Spek, G. Vankó, and D.C.
Koningsberger, J. Catal. 213 (2003) 251-271. Evolution of Fe Species during
the synthesis of overexchanged Fe/ZSM5 obtained by chemical vapor
deposition of FeCl3.
59 C. Boissière, M.A.U. Martines, P.J. Kooyman, T.R. de Kruijff, A. Larbot and E.
Prouzet, Chem. Mater. 15 (2003) 460-463. Ultrafiltration membrane made
with mesoporous MSU-X silica.
60 F. Devred, B. Hoffer, W.G. Slooff, A.D. van Langeveld, P.J. Kooyman and H.W.
Zandbergen, Proceedings NCCC VI, Noordwijkerhout, The Netherlands,
March 10-12, 2003 p. 212. Raney-type nickel catalysts: an XRD and XPS
study.
61 L. Qu, W. Zhang, P.J. Kooyman, and R. Prins, J. Catal. 215 (2003) 7-13. MAS
NMR, TPR, and TEM studies of NiMo with alumina and silica-alumina
supports.
62 F. Devred, B.W. Hoffer, W.G. Slooff, P.J. Kooyman, A.D. van Langeveld, and
H.W. Zandbergen, Appl. Catal. A: General 244 (2003) 291-300. The genesis
of the active phase in Raney-type catalysts: the role of leaching parameters.
63 J. Cinibulk, P.J. Kooyman, Z. Vít and M. Zdrazil, Catal. Lett. 89 (2003)
147-152. Magnesia supported Mo, CoMo and NiMo sulfide catalysts prepared
by non-aqueous impregnation: parallel HDS/HDN of thiophene and pyridine
and TEM microstructure.
64 L.J. Simon, P.J. Kooyman, J.G. van Ommen and J.A. Lercher, Appl. Catal. A:
General 252 (2003) 283-293. Effect of Co and Ni on benzene hydrogenation
and sulfur tolerance of Pt/H-MOR.
65 P.J. Kooyman, P. Waller, A.D. van Langeveld, C. Song, K. Reddy and J.A.R.
van Veen, Catal. Lett. 90 (2003) 131-135. Stability of MCM-41 supported
CoMo hydrotreating catalysts.
66 E. Crezee, P.J. Kooyman, J. Kiersch, W.G. Sloof, G. Mul, F. Kapteijn and J.A.
Moulijn, Catal. Lett. 90 (2003) 181-186. Dispersion and distribution of
ruthenium on carbon-coated ceramic monolithic catalysts prepared by
impregnation.
67 B.W. Hoffer, E. Crezee, F. Devred, P.R.M. Mooijman, W.G. Sloof, P.J.
Kooyman, A.D. van Langeveld, F. Kapteijn and J.A. Moulijn, Appl. Catal. A:
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General 253 (2003) 437-452. The role of the active phase of Raney-type Ni
catalysts in the selective hydrogenation of D-glucose to D-sorbitol.
68 Q. Sun, P.J. Kooyman, J.G. Grossmann, P.H.H. Bomans, P.M. Frederik,
P.C.M.M. Magusin, T.P.M. Beelen, R.A. van Santen and N.A.J.M.
Sommerdijk, Adv. Mater. 15 (2003) 1097-1100. The formation of highly
monodisperse hollow silica spheres with multilamellar shell structure.
69 P.J. Kooyman, S. Helveg, and A. Boisen, Proceedings of the NVvM 2003
meeting in Papendal, Arnhem, Dec 11-12 2003. In situ TEM reduction of
supported Cu-Pt nanoparticles.
2004
70 E.J.M. Hensen, Q. Zhu, M.M.R.M. Hendrix, A.R. Overweg, P.J. Kooyman,
M.V. Sychev and R.A. van Santen, J. Catal. 221 (2004) 560-574. Effect of
high-temperature treatment on Fe/ZSM-5 prepared by chemical vapour
deposition of FeCl3. I. Physicochemical characterisation.
71 J. Rathousky, M. Zukalova, P.J. Kooyman and A. Zukal, J. Coll. Surf. A 241
(2004) 81-86. Synthesis and characterisation of colloidal MCM-41.
72 M.F. Ottaviani, A. Moscatelli, D. Desplantier-Giscard, F. Di Renzo, P.J.
Kooyman, B. Alonso and A. Galarneau, J. Phys. Chem. B 108 (2004)
12123-12129. Synthesis of micelle-templated silicas from
cetyltrimethylammonium bromide / 1,3,5-trimethylbenzene micelles.
73 V. Hulea, D. Brunel, A. Galarneau, F. Fajula, K. Philippot, B. Chaudret and P.J.
Kooyman, Proceedings 4th International Mesostructured Materials
Symposium, Cape Town, May 1-4 2004 P-71. Synthesis of well-dispersed
ruthenium nanoparticles inside mesoporous MCM-41 materials under mild
conditions.
77 N. van Landschoot, E.M. Kelder, P.J. Kooyman, C. Kwakernaak and J.
Schoonman, J. Power Sources 138 (2004) 262-270. Electrochemical
performance of Al2O3-coated Fe doped LiCoVO4.
2005
78 M.A.U. Martines, E. Yeong, M. Persin, A. Larbot, W.F. Voorhout, C.K.U.
Kübel, P.J. Kooyman and E. Prouzet, C. R. Chimie 8 (2005) 187-194.
Hexagonal mesoporous silica nanoparticles with large pores and a
hierarchical porosity tested for HPLC.
79 V. Hulea, D. Brunel, A. Galarneau, K. Philippot, B. Chaudret, P.J. Kooyman and
F. Fajula, MMM 79 (2005) 185-194. Synthesis of well-dispersed ruthenium
nanoparticles inside mesoporous MCM-41 materials under mild conditions.
80 J.B. Taboada, A.R. Overweg, I.W.C.E. Arends, P.J. Kooyman, and G. Mul, J.
Catal. 231 (2005) 56-66. Following the evolution of iron from framework to
extra-framework positions in isomorphously substituted [Fe,Al]MFI with 57Fe
Mössbauer spectroscopy.
81 E.A. de Graaf, G. Rothenberg, P.J. Kooyman, A. Andreini and A. Bliek, Appl.
Catal. A: General 287 (2005) 185-194. Pt0.02Sn0.003Mg0.06 on alumina: a
stable oxidative dehydrogenation catalyst.
82 G. Surendran, M.S. Tokumoto, E. Pena dos Santos, H. Remita, L. Ramos, P.J.
Kooyman, C.Valentim Santilli, C. Bourgaux, P. Dieudonné and E. Prouzet,
Chem. Mater. 17 (2005) 1505-1514. Highly swollen liquid crystals as new
reactors for the synthesis of nanomaterials.
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83 Y. Ji, A.J. van der Eerden, V. Koot, P.J. Kooyman, J.D. Meeldijk, B.M.
Weckhuysen and D.C. Koningsberger, J. Catal. 234 (2005) 376-384.
Influence of support ionicity on the hydrogen chemisorption of Pt particles
dispersed in Y zeolite. Consequences for Pt particle size determination using
the H/M method.
84 E.J.M. Hensen, Q. Zhu, R.A.J. Jansen, P.C.M.M. Magusin, P.J. Kooyman and
R.A. van Santen, J. Catal. 233 (2005) 123-135. Selective oxidation of benzene
to phenol with nitrous oxide over MFI zeolites. I. On the role of iron and
aluminum.
85 G. Surendran, G. Apostolescu, M.S. Tokumoto, E. Prouzet, L. Ramos, P.
Beaunier, P.J. Kooyman, A. Etcheberry and H. Remita, Small 1 (2005)
964-967. From self-assembly of platinum nanoparticles to nanostructured
materials.
86 J.B. Taboada, A.R. Overweg and P.J. Kooyman, Stud. Surf. Sci. Catal. 158
(2005) 27-34. Direct synthesis of mesoporous Fe-MFI zeolite.
87 U. Lafont, P.J. Kooyman, A. Galarneau, and F. Di Renzo, Stud. Surf. Sci.
Catal. 155 (2005) 355-366. Templated and non-templated routes to
mesoporous titanium dioxide.
88 A.M. Paulaime-van Donk, P.J. Kooyman and J.C. Jansen, Stud. Surf. Sci.
Catal. 158 (2005) 351-358. The introduction of carbon oligomers into the
framework of silicalite-1.
89 M.B. Thathagar, P.J. Kooyman, R. Boerleiden, E. Jansen, C.J. Elsevier and G.
Rothenberg, Adv. Synth. Catal. 137 (2005) 1965-1968. Pd nanoclusters in
Sonogashira cross-coupling: a true catalytic species?
90 S. van Donk, B. Weckhuysen, F. Kapteijn, P.J. Kooyman and E.J.M. Hensen,
Catal. Today 110 (2005) 189-190. Introduction (and editors of special issue).
2006
92 B. Toukoniitty, E. Toukoniitty, P. Mäki-Arvela, J.P. Mikkola, T. Salmi, D.Yu.
Murzin and P.J. Kooyman, Ultrasonics Sonochemistry 13 (2006) 68-75.
Effect of ultrasound in enantioselective hydrogenation of 1-phenyl-1,2-
propanedione: comparison of catalyst activation, solvents and supports.
93 A. Galarneau, J. Iapichella, K. Philippot, F. Di Renzo, P.J. Kooyman, O.
Terasaki and F. Fajula, Adv. Funct. Mater. 16 (2006) 1657-1667. Controlling
the morphology of mesostructured silicas by pseudomorphic transformation: a
route towards applications.
94 L. Laffont, C. Delacourt, P. Gibot, M.Y. Wu, P.J. Kooyman, C. Masquelier and
J.M. Tarascon, Chem. Mater. 18 (2006) 5520-5529. Study of the LiFePO4/
FePO4 two-phase system by high-resolution electron energy loss spectroscopy.
98 O. Muraza, E.V. Rebrov, T. Khimyak, B.F.G. Johnson, P.J. Kooyman, U. Lafont,
P.A. Albouy, M.H.J.M. de Croon and J.C. Schouten, Stud. Surf. Sci. Catal.
162 (2006) 167-174. Preparation and characterization of bimetallic catalysts
supported on mesoporous silica films.
2007
95 E.G. Vrieling, Q. Sun, M. Tian, P.J. Kooyman, W.W.C. Gieskes, R.A. van
Santen and N.A.J.M. Sommerdijk, PNAS 104 (2007) 10441-10446. Salinitydependent
diatom biosilicification implies an important role of external ionic
strength.
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96 J.B. Taboada, A.R. Overweg and P.J. Kooyman, Stud. Surf. Sci. Catal. 170
(2007) 355-362. Direct synthesis of mesoporous Fe-MFI zeolite.
2008
97 P.J. Kooyman and J.A.R. van Veen, Catalysis Today 130 (2008) 135–138. The
detrimental effect of exposure to air on supported MoS2.
99 O. Muraza, E.V. Rebrov, T. Khimyak, B.F.G. Johnson, P.J. Kooyman, U. Lafont,
P.A. Albouy, M.H.J.M. de Croon and J.C. Schouten, Chemical Engineering
Journal 135S (2008) S99–S103. Mesoporous silica films as catalyst support
for microstructured reactors: Preparation and characterization.
100 M. Mirdamadi-Esfahani, M. Mostafavi, B. Keita, L. Nadjo, P.J. Kooyman, A.
Etcheberry, M. Imperor and H. Remita, Gold Bulletin 41 (2008) 98-104. Au-
Fe system: application in electrocatalysis.
101 D. Ortiz de Zarate, F. Bouyer, H. Zschiedrich, P.J. Kooyman, P. Trens, J.
Iapichella, R. Durand, C. Guillem and E. Prouzet, Chem. Mater. 20 (2008)
1410-1420. Micromesoporous monolithic Al-MSU with a widely variable
content of aluminum leading to tunable acidity.
102 E. de Smit, I. Swart, J.F. Creemer, G.H. Hoveling, M.K. Gilles, T. Tyliszczak,
P.J. Kooyman, H.W. Zandbergen, C. Morin, B.M. Weckhuysen and F.M.F. de
Groot, Nature 456 (2008) 222-225. Nanoscale chemical imaging of a working
catalyst by scanning transmission X-ray microscopy.
2009
103 J.F. Creemer, S. Helveg, G.H. Hoveling, S. Ullmann, P.J. Kooyman, A.M.
Molenbroek, H.W. Zandbergen and P.M. Sarro, IEEE International
Conference on MEMS technical digest 22 (2009) 76-79. MEMS
nanoreactor for atomic-resolution microscopy of nanomaterials in their
working state.
104 S. Janbroers, T.R. de Kruijff, Q. Xu, P.J. Kooyman and H.W. Zandbergen,
Ultramicroscopy 109 (2009) 1105–1109. Preparation of carbon-free TEM
microgrids by metal sputtering.
105 M.A. Lélias, P.J. Kooyman, L. Mariey, L. Oliviero, A. Travert, J. van Gestel,
J.A.R. van Veen and F. Maugé, J. Catal. 267 (2009) 14-23. Effect of NTA
addition on the structure and activity of the active phase of cobaltmolybdenum
sulfide hydrotreating catalysts.
106 S. Janbroers, J.N. Louwen, H.W. Zandbergen and P.J. Kooyman, J. Catal. 268
(2009) 235-242. Insights into the nature of iron-based Fischer–Tropsch
catalysts from quasi in situ TEM-EELS and XRD.
113 Y. Li, Y. Guan, R.A. van Santen, P.J. Kooyman, I. Dugulan, C. Li and E.J.M.
Hensen, J. Phys. Chem. C 113 (2009) 21831–21839. Direct Hydrothermal
Synthesis of Iron-Containing Mesoporous Silica SBA-15: Potential as a
Support for Gold Nanoparticles.
2010
107 M. Mirdamadi-Esfahani, M. Mostafavi, B. Keita, L. Nadjo, P. Kooyman and H.
Remita, Gold Bull. 43 (2010) 49-56. Bimetallic Au-Pt nanoparticles
synthesized by radiolysis: Application in electro-catalysis.
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109 E. Talgorn, R.D. Abellon, P.J. Kooyman, J. Piris, T.J. Savenije, A. Goossens,
A.J. Houtepen and L.D. A. Siebbeles, ACS Nano 4 (2010) 1723–1731.
Supercrystals of CdSe Quantum Dots with High Charge Mobility and Efficient
Electron Transfer to TiO2.
110 J.F. Creemer, S. Helveg, P.J. Kooyman, A.M. Molenbroek, H.W. Zandbergen
and P.M. Sarro, J MEMS 19 (2010) 254-264. A MEMS Reactor for Atomic-
Scale Microscopy of Nanomaterials Under Industrially Relevant Conditions.
2011
108 B.M. Vogelaar, A.D. van Langeveld, P.J. Kooyman, C.M. Lok, R.L.C. Bonné
and J.A. Moulijn, Catal. Today 163 (2011) 20-26. Stability of metal
nanoparticles formed during reduction of alumina supported nickel and cobalt
catalysts.
111 S. Janbroers, P.A. Crozier, H.W. Zandbergen and P.J. Kooyman, Appl. Catal.
B: Environm 102 (2011) 521-527. A model study on the carburization
process of iron-based Fischer–Tropsch catalysts using in situ TEM–EELS.
112 Contribution to book: Chemie: voor een veilig en duurzaam leefklimaat -
interviews met wetenschappers over toepassingen en mogelijkheden, door
Emma van Laar in opdracht van VNCI/NWO.
2013
114 A.F. Pérez-Cadenas, C.H. Ros, S. Morales-Torres, M. Pérez-Cadenas, P.J.
Kooyman, C. Moreno-Castilla and F. Kapteijn, Carbon 56 (2013) 324-311.
Metal-doped carbon xerogels for the electro-catalytic conversion of CO2 to
hydrocarbons.
115 S. Vendelbo, P.J. Kooyman, J.F. Creemer, B. Morana, L. Mele, P. Dona, B.
Nelissen and S. Helveg, Ultramicroscopy 133 (2013) 72-79. Method for local
temperature measurement in a nanoreactor for in situ high-resolution electron
microscopy.
2014
116 E. Skupien, R.J. Berger, V.P. Santos, J. Gascon, M. Makkee, M.T. Kreutzer, P.J.
Kooyman, J.A. Moulijn and F. Kapteijn. Catalysts 4 (2014) 89-115. Inhibition
of Gold Based Catalyst in Benzyl Alcohol Oxidation: Understanding and
Remediation.
117 S. Vendelbo, C.F. Elkjaer, H. Falsig, I. Puspitasari, P. Dona, L. Mele, B.
Morana, R. van Rijn, B. Nelissen, J.F. Creemer, P.J. Kooyman and S. Helveg,
Nature Materials 13 (2014) 884-890. Atomic-scale visualisation of Pt
nanoparticles catalysing the oscillatory CO oxidation.
2015
118 L. van Haandel, G.M. Bremmer, P.J. Kooyman, J.A.R. van Veen, T. Weber,
E.J.M. Hensen. ACS Catalysis 5 (2015) 7276-7287. Structure−Activity
Correlations in Hydrodesulfurization Reactions over Ni-Promoted
MoxW(1−x)S2/Al2O3 Catalysts.
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2016
119 B.A. van Driel, P.J. Kooyman, K.J. van den Berg, A. Schmidt-Ott, J.Dik.
Microchemical Journal. A quick assessment of the photocatalytic activity of
TiO2 pigments - From lab to conservation studio!
Accepted: